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LEDs gain quality, efficiency boost using MOF phosphor

21 Aug 2015

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Light-emitting diodes (LEDs) have upped the ante in terms of lighting, that much is true. However, scientists are still finding new ways to improve on the quality of light that LEDs produce and to reduce their cost and make them environmentally friendlier. Now, a team led by Zhichao Hu and Jing Li of Rutgers University has been able to do just that in its design of a new white LED.

Blue LED coated with a MOF-based yellow phosphor

A blue LED coated with a MOF-based yellow phosphor (left) made by Rutgers researchers produces white light efficiently (right). Credit: Courtesy of Jing Li.

"LEDs are everywhere, making their way into our homes, offices and schools to replace fluorescent and incandescent lights," Hu said. "But it's not easy to make white LEDs. We make what's called a phosphor-converted LED by coating an LED of one colour with a phosphor material of a different colour."

Hu reported the work during a symposium organised by the Division of Inorganic Chemistry at the American Chemical Society national meeting in Boston.

The researchers started by developing a family of tetraphenylethylene-based chromophores that luminesce at different wavelengths depending on placing different functional groups on the phenyl rings, Hu explained. They then linked chromophores together with zinc atoms to form a 3D metal-organic framework. Immobilising the chromophores helps tune and stabilise their colour emission.



The Rutgers researchers can make any colour LED they want by coating different coloured LEDs with the different phosphors. The phosphor is excited by light produced by the underlying LED, and the mixture of the emissions from the LED and phosphor produce the desired colour of light. To make a white LED, they coated a blue LED with a MOF-based yellow phosphor made using a chromophore named H4tcbpe. The material has a performance level approaching that of the best commercially available phosphors, Hu said. In addition, it doesn't require an increasingly expensive rare-earth metal typically used in LED phosphors and avoids toxic cadmium selenide used in quantum dot-based LEDs. The Rutgers researchers have patented the technology and are testing the materials with commercial LED manufacturers.

Current inorganic luminescent materials can be very efficient and stable, but their luminescence properties often have limited tunability, commented Oleg Shchekin, senior director of device architecture at Philips Lumileds. The freedom to tune emission spectra, as the Rutgers team is doing, is therefore important for maximizing the efficiency of LEDs, Shchekin said. "This work is showing the feasibility of hybrid materials, where the inorganic component is leveraged for efficiency while the emission from the organic component is tuned over a wide range."

"Li's group at Rutgers has been a leader in developing framework-based luminescent materials," added Ram Seshadri, co-director of the materials research laboratory at the University of California. "A particularly exciting aspect of these newly developed materials lies in the ease with which they can be painted on flexible substrates, suggesting unusual lighting sources and geometries are possible."

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